if somebody really wanted to do an effective analysis, here's what i'd do.
sign up for a team in a neutral park. sign 2 catchers, with a PC difference of like 40. don't fiddle with your lineups, don't fiddle with your pitching staff. if a player needs a few off days to stay at 100%, distribute them evenly over the course of the season. start one catcher for half of the team games, the other catcher for the other half. if a pitcher gets hurt, replace him with the closest quality pitcher you can, same for a position player wrt glove. after ~ 10 seasons, you should have a ballpark estimate as to the value of PC.
the other option is this: track the game by game performance of each pitcher with each catcher in the lineup. i.e. if i'm starting my 85 PC guy, and the opponent goes 8 for 26 against him, tally it in a spreadsheet. if a defender saves a hit with a + play, add it to the pitcher's hit total. if a defender allows a baserunner with a - play, subtract it from the pitcher's hit total. throw out games played in parks with extreme effects. in due time you should have a pretty decent sample of how much each catcher affects each pitcher's OAV.