If you're looking for feedback on the idea (will it work, is it interesting, what are the flaws) then this is the right place to post.
If you're looking for sign-ups then you want the Theme League classifieds.
Assuming the former... a couple of things.
It's tough to fill theme leagues right now, even for experienced owners. For better or worse, some owners are hesitant to join theme leagues started by a newbie. So you might want to play in a few first, get your name out and get a feel for who runs a league well and how they do it.
Having said that,it's a solid idea. I think you'd get some variety in teams at 100mil. Probably less so at 140mil. I assume you wouldn't allow clones (so only one Walter Johnson).It doesn't really strike me as the most unique idea I've ever seen but it's still interesting.
Also, a lot of people don't like 16 team leagues. If you can't fill it at 24 then some people might settle, but why start with a goal of 16?