Not counting defunct worlds, there are only a dozen guys who have logged 400 wins.
There are a handful that may rival Martinez
Julio Aguilera from BBWAA 418 Wins/ 5235 Ks/ .209 BAA /5607 ip/ 11 CY awards/ 3 no hitters
Deivi Elcano from DiMaggio 410 Wins/ 5553 Ks/ .213 BAA/ 6125 ip/ 11 CY awards/ 2 no hitters
Walker Mays from Hornsby 411 W/ 4759 ks/ .203 BAA/ 4594 ip / 7 CY awards/ 6 WS rings
Del Tanaka from Hornsby 414 W/ 3379 Ks/ .197 BAA/ 4489 ip / 15 CY awards/ 10 WS rings
Albie Siqueiros from Ryan 459 Wins/ 2939 Ks/ .187 BAA/ 2951 ip/ 9 CY awards/ 10 WS rings
and IMO the best ever:
Luis Rodriguez from Cool Papa Bell 472 Wins/ 5224 Ks/ .185 BAA/ 5243 ip /14 CY awards/ 7 WS rings/ 3 no hitters including one perfect game.