Two theories:
1. We see what we think should be true.
2. We remember when something goes wrong.
Basically, one would think a guy adjusting to a new position might struggle at the plate a little because he's taking extra grounders instead of extra swings. He's carrying a bad play in the field to the plate. Something like that. Or a guy switches positions and declines at the plate. We notice it. A guy switches positions and remains the same or, better yet, hits better. Remaining the same isn't noteworthy and getting better just means he's finally hitting like he should. For every 1 "Is he overperforming?" sitemail I get, I get 20 "Why is this guy underperforming?" sitemails.