Short Answer - "No"
Longer answer - I would advise you not to make any decisions whatsoever based on ST stats. I personally try and accomplish only three things in ST - 1) Get my vets their 20 PA or 3 G/10IP to hold off decline (my numbers, others use different ones); 2) Play the prospects who I hope will someday make the ML the rest of the time; 3) Pray to avoid injuries.
In your specific case, I wouldn't make any decision based on a player having "only Single A experience" either. Looking at the two players, Player 2 has better ratings right now, but with only 3 years of pro ball, I'd keep him in AAA and keep his price tag down for at least another season to maximize his prime years with you. At the very least, he'd start in AAA for me and if I thought he'd be the difference between playoff and no playoffs, then I'd perhaps promote him at game 21.