I've had at least two players that I've signed not acknowledge my phone call (no message received but $10 spent and deducted for the call) who, after signings began, appeared as drop downs in my division and were receptive to recruiting at that time. Not quite the scenario you're asking about, i guess, but I would say there's at least a chance as long as you don't get a hard no (please stop calling me *SLAM*) type message that they can show up as recruitable later down the line in at least isolated instances.