I think, don't know how correct this is, that they would be categorized as effecting the shooting process for players. So I would say yes, it will decrease shooting percentage overall. That being said I don't think it's a big part of the equation, and would probably give up a lot on shot blocking if it meant picking up a couple extra points on defense.
Maybe an example will kind of clear that up but what I'm theorizing is that hypothetically ath sp and de would contribute to whether or not the offense is able to get a shot off, and ath sb and de are part of the does the shot go in or not category. I could be wrong and both these could be determined at once, which would make def and ath the overriding parts of the equation, which they do seem to be.